发明授权
US06409974B1 Water gas shift process and apparatus for purifying hydrogen for use with fuel cells 失效
用于燃料电池的用于净化氢的水煤气变换过程和装置

  • 专利标题: Water gas shift process and apparatus for purifying hydrogen for use with fuel cells
  • 专利标题(中): 用于燃料电池的用于净化氢的水煤气变换过程和装置
  • 申请号: US09210306
    申请日: 1998-12-11
  • 公开(公告)号: US06409974B1
    公开(公告)日: 2002-06-25
  • 发明人: Gavin P. TowlerKurt Vanden Bussche
  • 申请人: Gavin P. TowlerKurt Vanden Bussche
  • 主分类号: B01D5000
  • IPC分类号: B01D5000
Water gas shift process and apparatus for purifying hydrogen for use with fuel cells
摘要:
A process and apparatus are disclosed for the operation of a compact water gas shift reactor for use in conjunction with fuel cell to generate electric power from a feed stream comprising a hydrocarbon or an alcohol. The fuel cell comprises a proton exchange membrane which produces electric power from a hydrogen product stream which comprises essentially no carbon monoxide. The hydrogen product stream may produced from the feed stream in a steam reforming of autothermal reforming zone. The compact water gas shift reactor comprises a vertically aligned vessel having a top end, a bottom end opposite, which defines an interior space. The interior space contains a first water spray zone for contacting a reforming effluent stream comprising hydrogen with a first water stream. A first dispersion zone is disposed below the first water spray zone and above a high temperature shift zone. The high temperature shift zone contains a high temperature shift catalyst to produce a high temperature shift effluent stream. A second water spray zone is disposed below the high temperature shift zone and above a second dispersion zone. A low temperature shift zone is disposed below the second dispersion zone. The low temperature shift zone contains a low temperature shift catalyst to produce a water saturated hydrogen product stream which comprises less than 50 ppm-mol carbon monoxide. The water dispersion zones simplify the overall shift reaction zone and provide protection for the shift catalysts from temperature shock.
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