发明授权
- 专利标题: Incorporation of free radical inhibitors in polyolefins
- 专利标题(中): 在聚烯烃中引入自由基抑制剂
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申请号: US08920625申请日: 1997-08-27
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公开(公告)号: US06410629B1公开(公告)日: 2002-06-25
- 发明人: Michael J. Mullins , Peter N. Nickias , Jorge Soto
- 申请人: Michael J. Mullins , Peter N. Nickias , Jorge Soto
- 主分类号: C08K551
- IPC分类号: C08K551
摘要:
The invention includes a process for inhibiting deterioration in an olefin polymer by adding a phenolic free radical inhibitor during or before polymerization with a metallocene type transition metal catalyst without inactivating the free radical inhibitor because does not inhibit the transition metal catalyst activity. Preferably the free radical inhibitor is first to remove compounds which inhibit catalyst activity. The invention also includes a composition comprising at least one olefin monomer, a polymer of the monomer, a metallocene type transition metal catalyst and at least one free radical inhibitor having sufficient substituents to hinder the active inhibiting group such that it does not undesirably inhibit the transition metal catalyst.
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