发明授权
- 专利标题: Organometallic fluorenyl compounds, preparation, and use
- 专利标题(中): 有机金属芴基化合物,制备和使用
-
申请号: US08352936申请日: 1994-12-09
-
公开(公告)号: US06420579B1公开(公告)日: 2002-07-16
- 发明人: Helmut G. Alt , Syriac J. Palackal , Konstantinos Patsidis , M. Bruce Welch , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel , Gil R. Hawley , Paul D. Smith
- 申请人: Helmut G. Alt , Syriac J. Palackal , Konstantinos Patsidis , M. Bruce Welch , Rolf L. Geerts , Eric T. Hsieh , Max P. McDaniel , Gil R. Hawley , Paul D. Smith
- 主分类号: C07F1700
- IPC分类号: C07F1700
摘要:
Bridged and unbridged fluorenyl-containing metallocenes of the formula R″x(FlRn)(CpRm)MQk wherein Fl is a fluorenyl radical, Cp is a cyclopentadienyl, indenyl, tetrahydroindenyl, or fluorenyl radical, each R is an organo radical, R″ is a structural bridge linking (FlRn) and (CpRm), M is a metal selected from the group consisting of IVB, VB, and VIB metals, each Q is selected from the group consisting of hydrocarbyl or hydrocarbyloxy radicals and halogen, x is 1 or 0, k is an integer sufficient to fill out the remaining valences of M, n is in the range of 0 to 7, and m is 0 to 7, further characterized by the fact that if (CpRm) is unsubstituted fluorenyl and metallocene is an unbridged metallocene, then n is 1 to 7 and if R″ is 1,1-dimethylmethylene and (CpRm) is unsubstituted cyclopentadienyl or 3-methylcyclopentadienyl, then n is 1 to 7.
信息查询