发明授权
- 专利标题: Production process for hydroxyalkyl(meth)acrylate
- 专利标题(中): (甲基)丙烯酸羟烷基酯的制备方法
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申请号: US09664953申请日: 2000-09-16
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公开(公告)号: US06458988B1公开(公告)日: 2002-10-01
- 发明人: Hajime Matsumoto , Tokumasa Ishida , Yasuhiro Shingai , Masatoshi Ueoka , Yukihiro Yoneda
- 申请人: Hajime Matsumoto , Tokumasa Ishida , Yasuhiro Shingai , Masatoshi Ueoka , Yukihiro Yoneda
- 优先权: JP11-285887 19991006; JP11-285888 19991006; JP2000-022692 20000131; JP2000-032340 20000209
- 主分类号: C07C6726
- IPC分类号: C07C6726
摘要:
A production process for a hydroxyalkyl(meth)acrylate, which comprises the steps of carrying out a reaction between (meth)acrylic acid and an alkylene oxide and stripping the unreacted residue of the alkylene oxide from the resultant reaction liquid, wherein: (1) the stripping step is performed by use of an inert gas, and the concentration of oxygen in the inert gas is adjusted in the range of 0.1 to 5 mol %; (2) the concentration of the unreacted residue of the (meth)acrylic acid in the resultant reaction liquid is suppressed to not higher than 10 weight %; (3) the difference in operational pressure between the stripping step and the absorption step of causing a solvent to absorb the stripped alkylene oxide is suppressed to not more than 1,000 hPa; (4) the reaction liquid resultant from the reaction is directly supplied to the stripping step without being heated; (5) a part of the liquid left behind in the stripping step is heated and then supplied to the stripping step again; (6) a hydroxyalkyl (meth)acrylate solution is used as the absorbing solvent; (7) a part of the liquid resultant from the absorption step is cooled and then supplied to the absorption step again; or (8) a part or the whole of the absorbing liquid which is on the way of the absorption step is extracted and then cooled and then supplied to the absorption step again.
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