Structures and methods are provided for deriving corrected star coordinates Ccrctd from measured star coordinates Cms that include star tracker charge transfer efficiency (CTE) errors. The structures and methods are based on a recognition that measured star coordinates Cms of star image centroids include CTE errors which are functions of the CCD path lengths over which the associated electrical charges traveled. In particular, the errors are substantially a product of a respective path length and a star-coordinate error factor &xgr; which, in turn, is a function of the star image magnitudes msi. Information contained in different measured star coordinates Cms is organized to facilitate the derivation of an estimate &xgr;* of the star-coordinate error factor &xgr; with conventional estimation processes. The measured star coordinates Cms are then corrected with the error factor estimate &xgr;* to realize the corrected star coordinates Ccrctd and, thereby, improve the accuracy of spacecraft attitude control.