A method of manufacturing a semiconductor device includes: providing a semiconductor with a dielectric layer formed thereon; forming an opening in said dielectric layer, said opening defined by walls of said dielectric layer and exposes a portion of said semiconductor, forming a conductive layer in said opening; removing said conductive layer to said dielectric layer; and forming a barrier layer over said conductive layer and said dielectric layer, said barrier layer made of a compound of silicon nitride with a third material compounded therein wherein said third material is modulated in amount through said layer of silicon nitride.