发明授权
- 专利标题: Multistage process for the preparation of oxo aldehydes and/or alcohols
- 专利标题(中): 用于制备羰基醛和/或醇的多步法
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申请号: US09904893申请日: 2001-07-16
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公开(公告)号: US06482992B2公开(公告)日: 2002-11-19
- 发明人: Bernhard Scholz , Franz Nierlich , Alfred Kaizik , Dieter Hess , Wilfried Bueschken , Klaus-Diether Wiese , Dirk Roettger , Guido Protzmann
- 申请人: Bernhard Scholz , Franz Nierlich , Alfred Kaizik , Dieter Hess , Wilfried Bueschken , Klaus-Diether Wiese , Dirk Roettger , Guido Protzmann
- 优先权: DE10034360 20000714
- 主分类号: C07C4550
- IPC分类号: C07C4550
摘要:
Olefins are hydroformylated to give alcohols and/or aldehydes in a plurality of hydroformylation stages, each of which comprises: a) hydroformylating olefins having a carbon atom content of 6 to 24 carbon atoms in the presence of a cobalt- or rhodium catalyst in a reactor to the point of conversion of olefin reactant to product of 20 to 98%; b) removing the catalyst from the resulting liquid discharged from the reactor; c) separating the resulting liquid hydroformylation mixture into a low-boiler fraction comprising olefins and paraffins, and a bottoms fraction comprising aldehydes and/or alcohols; and d) reacting the olefins present in the low-boiler fraction in subsequent process stages comprising steps a, b and c and combining the bottoms fractions of process steps c) of all process stages.
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