发明授权
- 专利标题: Preparation of C5-/C6-olefins
- 专利标题(中): 制备C5- / C6-烯烃
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申请号: US09610942申请日: 2000-07-06
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公开(公告)号: US06538168B1公开(公告)日: 2003-03-25
- 发明人: Peter Schwab , Michael Schulz , Ralf Schulz , Sylvia Huber
- 申请人: Peter Schwab , Michael Schulz , Ralf Schulz , Sylvia Huber
- 优先权: DE19932060 19990712
- 主分类号: C07C602
- IPC分类号: C07C602
摘要:
A process for preparing C5/C6-olefins from an olefinic starting stream comprising C4-hydrocarbons comprises a) carrying out a metathesis reaction in the presence of a metathesis catalyst so as to convert the 1-butene, 2-butene and isobutene present in the starting stream into a mixture of C2-C6-olefins and butanes, b) firstly fractioning the resulting product stream by distillation to give a low boiler fraction A comprising C2-C4-olefins and butanes or C2-C3-olefins, which is discharged, and a high boiler fraction comprising C4-C8-olefins and butanes, c) fractioning the high boiler fraction from b) by distillation to give a low boiler fraction B comprising butenes and butanes, an intermediate boiler fraction C comprising pentene and methylbutene and a high boiler fraction D comprising hexane and methylpentene, d) where all or part of the fraction B and/or C are recirculated to the process step a) and the fraction D is discharged as product.
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