发明授权
- 专利标题: Bisphosphite compounds and their metal complexes
- 专利标题(中): 二亚磷酸酯化合物及其金属络合物
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申请号: US09984263申请日: 2001-10-29
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公开(公告)号: US06570033B2公开(公告)日: 2003-05-27
- 发明人: Dirk Röttger , Dieter Hess , Klaus-Diether Wiese , Cornelia Borgmann , Armin Börner , Detlef Selent , Reinhard Schmutzler , Christine Kunze
- 申请人: Dirk Röttger , Dieter Hess , Klaus-Diether Wiese , Cornelia Borgmann , Armin Börner , Detlef Selent , Reinhard Schmutzler , Christine Kunze
- 优先权: DE10053272 20001027
- 主分类号: C07F908
- IPC分类号: C07F908
摘要:
A bisphosphite of the formula I wherein R1, R2, R3 and R4 are each hydrogen, an aliphatic, alicyclic, aliphatic-alicyclic, aromatic, aromatic—aromatic, aliphatic-aromatic hydrocarbon or heterocyclic or aliphatic-heterocyclic group having from 1 to 50 carbon atoms, F, Cl, Br, I, —CF3, —OR7, —COR7, —CO2R7, —CO2M, —SR7, —SO2R7, —SOR7, —SO3R7, —SO3M, —CO2NR7R8, NR7R8, N═CR7R8, NH2, where R1 to R4 are identical or different and may be covalently linked to one another; R7 and R8 are each hydrogen, a substituted or unsubstituted, aliphatic or aromatic hydrocarbon radical having from 1 to 25 carbon atoms, and may be identical or different; M is an alkali metal, alkaline earth metal, ammonium or phosphonium ion; Q is a substituted or unsubstituted divalent aliphatic, alicyclic, aliphatic-alicyclic, aromatic, aliphatic-aromatic hydrocarbon, heterocyclic or aliphatic-heterocyclic radical having from 1 to 50 carbon atoms where HO-Q-OH is a diol; W and X are each a substituted or unsubstituted aliphatic, alicyclic, aliphatic-alicyclic, aromatic, aromatic—aromatic, aliphatic-aromatic hydrocarbon, heterocyclic or aliphatic-heterocyclic radical having from 1 to 50 carbon atoms which may be identical or different or covalently linked to one another, provided that when the phosphite oxygens linked to W and X are each linked to an aromatic ring, then they are linked to different aromatic rings, metal complexes thereof, and a method for the hydroformylation of olefins.
公开/授权文献
- US20020111487A1 Novel bisphosphite compounds and their metal complexes 公开/授权日:2002-08-15
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