发明授权
US06573350B1 Branched semi-crystalline high-C3 ethylene-propylene compositions
有权
支化半结晶高C3乙烯 - 丙烯组合物
- 专利标题: Branched semi-crystalline high-C3 ethylene-propylene compositions
- 专利标题(中): 支化半结晶高C3乙烯 - 丙烯组合物
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申请号: US09461797申请日: 1999-12-15
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公开(公告)号: US06573350B1公开(公告)日: 2003-06-03
- 发明人: Eric J. Markel , Weiqing Weng , Armenag H. Dekmezian
- 申请人: Eric J. Markel , Weiqing Weng , Armenag H. Dekmezian
- 主分类号: C08F464
- IPC分类号: C08F464
摘要:
Branched ethylene-propylene compositions which have improved melt strength and shear thinning are provided. The weight average branching index g′ for the higher molecular weight region of the ethylene-propylene composition is less than 0.95. Additionally, a novel process is provided for efficiently producing a branched ethylene-propylene composition comprising: a) contacting propylene monomers and ethylene monomers in a reactor with an inert hydrocarbon solvent or diluent and a catalyst composition comprising one or more single site catalyst compounds capable of producing an ethylene-propylene polymer at a temperature from about 50° C. to about 180° C., wherein the ratio in the reactor of the propylene and ethylene monomers to the inert hydrocarbon solvent or diluent is less than 2.0, and further, wherein the propylene and ethylene monomers and the inert hydrocarbon solvent or diluent comprise no more than 90 percent of the total contents of the reactor; and b) recovering a branched ethylene-propylene composition, wherein the weight average branching index g′ for the higher molecular weight region of the ethylene-propylene composition is less than 0.95.
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