发明授权
US06590048B1 Highly active cationic ruthenium and osmium complexes for olefin metathesis reactions
失效
用于烯烃复分解反应的高活性阳离子钌和锇络合物
- 专利标题: Highly active cationic ruthenium and osmium complexes for olefin metathesis reactions
- 专利标题(中): 用于烯烃复分解反应的高活性阳离子钌和锇络合物
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申请号: US09555652申请日: 2001-01-02
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公开(公告)号: US06590048B1公开(公告)日: 2003-07-08
- 发明人: Alois Fürstner , Pierre Dixneuf , Christian Bruneau , Michel Picquet
- 申请人: Alois Fürstner , Pierre Dixneuf , Christian Bruneau , Michel Picquet
- 优先权: EP97121228 19971203
- 主分类号: C07C604
- IPC分类号: C07C604
摘要:
The present invention describes the use of cationic vinylidene, allenylidene and higher cumulenylidene complexes of ruthenium or osmium as catalysts or catalyst precursors for olefin metathesis reactions of all types, as well as to new cationic allenylidene complexes of ruthenium and osmium which can be used as metathesis catalysts with preferred embodiment. These catalysts or catalyst precursors are easy to prepare from well accessible, stable and essentially non toxic starting materials, can be isolated and stored, they exhibit a high catalytic activity, a good compatibility with functional groups, solvents, water and additives, and they need not to be activated by any additive. Olefins of all types can be used as the substrates in the present invention in ring closing metathesis (RCM) of acyclic dienes and polyenes, the metathesis of enynes and dienynes, the ring opening metathesis polymerization (ROMP) of cyclic olefins, the acyclic diene metathesis polymerization (ADMET) of acyclic dienes or polyenes, the depolymerization of olefinic polymers, and the cross metathesis of two or more olefins. The present invention also applies to combinations of these types of metathetic reactions and domino processes thereof.
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