Fuel cell electrodes comprising a minimal load of catalyst having maximum catalytic activity and a method of forming such fuel cell electrodes. The preferred method comprises vaporizing a catalyst, preferably platinum, in a vacuum to form a catalyst vapor. A catalytically effective amount of the catalyst vapor is deposited onto a carbon catalyst support on the fuel cell electrode. The electrode preferably is carbon cloth. The method reduces the amount of catalyst needed of a high performance fuel cell electrode to about 0.3 mg/cm2 or less, preferably to about 0.1 mg/cm2. The electrocatalytic layer formed comprises unique, rod-like structures.