发明授权
US06624272B2 HOLLOW CROSSLINKED CATIONIC POLYMER PARTICLES, METHOD OF PRODUCING SAID PARTICLES, AND PAINT COMPOSITION, CATIONIC ELECTRODEPOSITION PAINT COMPOSITION, RESIN COMPOSITION, FILLED PAPER, PAPER COATING COMPOSITION, AND COATED PAPER
有权
中空交联阳离子聚合物颗粒,生产颗粒的方法和涂料组合物,阳离子电沉积涂料组合物,树脂组合物,填充纸,纸涂料组合物和涂布纸
- 专利标题: HOLLOW CROSSLINKED CATIONIC POLYMER PARTICLES, METHOD OF PRODUCING SAID PARTICLES, AND PAINT COMPOSITION, CATIONIC ELECTRODEPOSITION PAINT COMPOSITION, RESIN COMPOSITION, FILLED PAPER, PAPER COATING COMPOSITION, AND COATED PAPER
- 专利标题(中): 中空交联阳离子聚合物颗粒,生产颗粒的方法和涂料组合物,阳离子电沉积涂料组合物,树脂组合物,填充纸,纸涂料组合物和涂布纸
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申请号: US09739257申请日: 2000-12-19
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公开(公告)号: US06624272B2公开(公告)日: 2003-09-23
- 发明人: Satoshi Futami , Kouji Tamori , Katsuhiko Tsuruoka
- 申请人: Satoshi Futami , Kouji Tamori , Katsuhiko Tsuruoka
- 优先权: JP11-360852 19991220; JP11-371370 19991227; JP2000-015028 20000124; JP2000-015029 20000124; JP2000-015030 20000124; JP2000-025694 20000202; JP2000-053351 20000229
- 主分类号: C08F23612
- IPC分类号: C08F23612
摘要:
An object of the present invention is to provide cationic hollow crosslinked polymer particles that maintain a cationic property over a wide pH range, has adequate strength, and is favorable for use in filled paper, pigments for coating paper, additives for paints, fillers for resins, rubbers, and the like. Another object of the present invention is to provide a method of producing the abovementioned cationic hollow crosslinked polymer particles with excellent characteristics in a stable manner. The hollow crosslinked polymer particles of the present invention are characterized in that (I) the zeta potential as measured in an aqueous medium of pH 2 to 9 is in the range of +5 to +100 mV, (II) the volume hollowness is in the range of 1 to 80%, and (III) the average particle diameter is in the range of 0.03 to 10 &mgr;m. This hollow crosslinked polymer particles are produced by a method that (a) 1 to 99.99 weight % of a crosslinking monomer, (b) 0.01 to 15 weight % of a cationic monomer, and (c) 0 to 98.99 weight % of a copolymerizable monomer that is non-crosslinking and nonionic (the total amount of the monomers being 100 weight %) are polymerized under the presence of polymer particles that are swellable by at least one of the above monomers. This hollow crosslinked cationic polymer particles are utilized for paint composition, cationic electrodeposition paint composition, resin composition, filled paper, paper coating composition, and coated paper, and the like.
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