发明授权
US06653430B1 Butadiene polymers and process for producing conjugated diene polymers
失效
丁二烯聚合物和共轭二烯聚合物的制备方法
- 专利标题: Butadiene polymers and process for producing conjugated diene polymers
- 专利标题(中): 丁二烯聚合物和共轭二烯聚合物的制备方法
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申请号: US09601469申请日: 2001-06-18
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公开(公告)号: US06653430B1公开(公告)日: 2003-11-25
- 发明人: Kazuo Soga , Michihiko Asai , Yasuzo Suzuki , Akira Miyazawa , Kenji Tsuchihara , Masahide Murata , Hiroyuki Ozaki , Masanao Kawabe , Yoshifumi Fukui , Jizhy Jin , Hideaki Hagihara , Toshio Kase
- 申请人: Kazuo Soga , Michihiko Asai , Yasuzo Suzuki , Akira Miyazawa , Kenji Tsuchihara , Masahide Murata , Hiroyuki Ozaki , Masanao Kawabe , Yoshifumi Fukui , Jizhy Jin , Hideaki Hagihara , Toshio Kase
- 优先权: JPH10-38140 19980204; JPH10-38141 19980204; JPH10-280517 19980915; JPH10-280518 19980915; JPH10-280519 19980915; JPH10-280520 19980915
- 主分类号: C08F3606
- IPC分类号: C08F3606
摘要:
A butadiene polymer (i) having a cis bond unit content of at least 50% based on the total butadiene units, a number average molecular weight (Mn) of 1,000 to 10,000,000, and at least 80%, based on the total molecular chains, of living chains containing a transition metal of group IV of the Periodic table at a terminal thereof; a polymer (ii) obtained by modifying terminals of the polymer (i); and a polymer (iii) obtained by coupling the polymers (i). These polymers (i), (ii) and (iii) are obtained by polymerizing a conjugated diene monomer alone or with a copolymerizable monomer at a specific temperature in the presence of a catalyst comprising a compound (A) of a transition metal of group IV of the periodic table having a cyclopentadienyl structure and a co-catalyst (B) selected from organoaluminum-oxy compound (a) and others and optionally further by contacting the resultant polymer with a terminal modifier or a coupling agent.
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