Invention Grant
- Patent Title: Polymerization catalysts
- Patent Title (中): 聚合催化剂
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Application No.: US09830229Application Date: 2001-04-24
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Publication No.: US06677267B2Publication Date: 2004-01-13
- Inventor: Alain Berardi , John Gabriel Speakman
- Applicant: Alain Berardi , John Gabriel Speakman
- Priority: EP98430023 19981026
- Main IPC: B01J3118
- IPC: B01J3118

Abstract:
The present invention relates to a process for the polymerization and copolymerization of 1-olefins and to a catalyst to be used in said process wherein the catalyst comprises (1) a complex having formula (I) wherein M is Fe[II], Fe[III], Co[I], Co[II], Co[III], Mn[I], Mn[II], Mn[III], Mn[IV], Ru[II], Ru[III] or Ru[IV]; X represents an atom or group covalently or ionically bonded to the metal M; T is the oxidation state of the metal; b is the valency of the atom or group X; and R 1 to R 7 are each independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl, substituted heterohydrocarbyl or SiR′ 3 where each R′ is independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl, substituted heterohydrocarbyl; and when any two or more of R 1 to R 7 are hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, said two or more can be linked to form one or more cyclic substituents; (2) an activator which is an alkylalumoxane; and (3) a support material, wherein the atomic ratio of aluminium in the alkylalumoxane (2) to transition metal M in (1) is from 6:1 to 25:1.
Public/Granted literature
- US20020035031A1 Polymerisation catalysts Public/Granted day:2002-03-21
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