发明授权
US06692545B2 Combined water gas shift reactor/carbon dioxide adsorber for use in a fuel cell system
有权
用于燃料电池系统的组合式水煤气变换反应器/二氧化碳吸附器
- 专利标题: Combined water gas shift reactor/carbon dioxide adsorber for use in a fuel cell system
- 专利标题(中): 用于燃料电池系统的组合式水煤气变换反应器/二氧化碳吸附器
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申请号: US09780079申请日: 2001-02-09
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公开(公告)号: US06692545B2公开(公告)日: 2004-02-17
- 发明人: Craig S. Gittleman , Ramesh Gupta
- 申请人: Craig S. Gittleman , Ramesh Gupta
- 主分类号: C10K302
- IPC分类号: C10K302
摘要:
An apparatus removes CO from a hydrogen-rich gas stream in a hydrogen fuel cell system. CO fouls costly catalytic particles in the membrane electrode assemblies. Both a catalyst adapted to perform a water gas shift reaction, and a carbon dioxide adsorbent are disposed in a rotating pressure swing adsorber housing. The adsorption of carbon dioxide shifts equilibrium toward carbon monoxide consumption. A second adsorbent may be disposed in the housing for adsorbing carbon monoxide at low temperatures, and is adapted to desorb carbon monoxide at high temperatures. The present invention advantageously eliminates a unit operation from a space-constrained fuel cell vehicle by combining the WGS catalyst and a CO2 adsorbent in a single reactor/housing. The apparatus further eliminates the use of a PROX reactor, by providing an apparatus which incorporates CO2 adsorption and consequent carbon monoxide consumption in the place of the PROX reactor.
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