发明授权
- 专利标题: Process of preparing halogenated esters
- 专利标题(中): 制备卤代酯的方法
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申请号: US10117241申请日: 2002-04-05
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公开(公告)号: US06703520B2公开(公告)日: 2004-03-09
- 发明人: Klaus Hintzer , Egon Obermaier , Werner Schwertfeger
- 申请人: Klaus Hintzer , Egon Obermaier , Werner Schwertfeger
- 优先权: EP01201473 20010424
- 主分类号: C07C20500
- IPC分类号: C07C20500
摘要:
The present invention provides a process for preparing a desired halogenated ester, which process comprises the steps of: (a) contacting (A) a substantially organic solvent free liquid mixture of (i) an alkanolate of the formula M—O—Z, wherein M is an alkali or alkaline earth metal, and Z is a linear, branched or cyclic alkyl group of 1 to 10 carbon atoms and (ii) a diester with (B) a halogenated ethylenically unsaturated olefin at a temperature of not more than 40° C. and with a mol ratio of halogenated ethylenically unsaturated olefin to alkanolate of not more than 1.1; (b) contacting an acid with a thus obtained reaction mixture thereby obtaining a mixture comprising the desired halogenated ester; and (c) recovering the halogenated ester from said reaction mixture. In step (a) of the process, the mixture of the alkanolate and diester is contacted with the halogenated ethylenically unsaturated olefin under conditions of agitation sufficient such that the weight ratio of halogenated ester to halogenated ketone as a byproduct obtained after step (b) is at least 10:1.
公开/授权文献
- US20020177729A1 Process of preparing halogenated esters 公开/授权日:2002-11-28