A memory card ejecting structure includes an electrically insulative frame base, the frame base having a receiving unit mounted with a set of terminals for receiving a memory card and two arms forwardly extended from two opposite lateral sides of the receiving unit, the receiving unit having an endless guide groove, an ejecting member slidably mounted in the frame base and adapted for ejecting the inserted memory card out of the receiving unit, and a spring member connected between the ejecting member and one arm of the frame base, the spring member having an angled locating wire rod backwardly extended from a rear end ring thereof and positioned in the endless guide groove to hold the spring member between a stretched position and a released position.