A refrigerator with a multipurpose storage chamber and a control method. In the refrigerator, the flow of cool air to the multipurpose storage chamber is selectively controlled in accordance with a variety of operational modes. In order to accomplish such a cool air flow control, a refrigerating compartment fan and a damper are provided at positions above a refrigerating compartment evaporator. In addition, a flap, controlled at an open angle thereof, is provided at the inlet of an air guide path guiding the cool air to the multipurpose storage chamber. The multipurpose storage chamber of this refrigerator can thus effectively be used to store a variety of foods in accordance with storage characteristics of the foods. In addition, a thawing mode operation of the refrigerator is performed under the condition that it is not necessary to perform a refrigerating compartment cooling operation. It is thus possible to prevent an excessive increase in the temperature of the refrigerating compartment caused by an operation of the defrosting heater during such a thawing mode.