An organic electroluminescence device is made to show an improved carrier transporting ability and an improved carrier injecting property by doping a liquid crystal compound having a high degree of carrier mobility without generating any ionic current. The organic electroluminescence device comprises a carrier transport layer formed by doping a smectic liquid crystal compound having a hexagonal order structure with a Lewis acid compound, a light-emitting layer and a protection layer arranged between the carrier transport layer and the light-emitting layer and composed of an organic compound having a carrier transporting property of the same type as that of carrier transport layer and a carrier conducting property of the type different from that of the carrier transport layer.