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US06743871B2 Method for polymerising ethylene 失效
聚合乙烯的方法

  • 专利标题: Method for polymerising ethylene
  • 专利标题(中): 聚合乙烯的方法
  • 申请号: US10258538
    申请日: 2003-05-05
  • 公开(公告)号: US06743871B2
    公开(公告)日: 2004-06-01
  • 发明人: Giuliano BertozziFabian Siberdt
  • 申请人: Giuliano BertozziFabian Siberdt
  • 优先权: ITMI2001A0405 20010228
  • 主分类号: C08F444
  • IPC分类号: C08F444
Method for polymerising ethylene
摘要:
The invention concerns a method for producing ethylene homopolymers or copolymers comprising at least 90 mol % of units derived from ethylene which consists in: contacting in polymerising conditions, the monomers with a catalytic system including: (a) a catalytic solid comprising a metallocene of a transition metal of groups 4 to 6 of the periodic table containing at least a cyclopentadiene ligand capable of being substituted and a support, (b) at least an organoaluminium compound selected among compounds of general formula (1): AlTx(Y′)yX′z wherein: T is a hydrocarbon group containing 1 to 30 carbon atoms; Y′ is a group selected among —OR′, —SR′ and NR′R″ with R′ and R″ independently representing a hydrocarbon group containing 1 to 30 carbons atoms; X′ is a halogen atom: x verifies the relationship 0
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