发明授权
- 专利标题: Process for the preparation of heat-stable, antimony-free polyesters of neutral color and the products which can be prepared by this process
- 专利标题(中): 用于制备中性色热稳定,无锑聚酯的方法以及可通过该方法制备的产品
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申请号: US08520662申请日: 1995-08-28
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公开(公告)号: US06787630B1公开(公告)日: 2004-09-07
- 发明人: Ligia Dominguez De Walter , Banks Bryan Moore , Peter Klein
- 申请人: Ligia Dominguez De Walter , Banks Bryan Moore , Peter Klein
- 优先权: DE4430634 19940829
- 主分类号: C08G6382
- IPC分类号: C08G6382
摘要:
Process for the preparation of heat-stable, antimony-free polyesters of neutral color and the products which can be prepared by this process A process for the preparation of heat-stable, antimony-free polyesters of neutral color by esterification of aromatic dicarboxylic acids or transesterification of lower aliphatic esters of aromatic dicarboxylic acids with aliphatic diols and subsequent polycondensation in which a possible transesterification is carried out in the presence of 20 to 120 ppm, based on the catalyst metal, of a transesterification catalyst, after the esterification or transesterification has ended, phosphoric acid, phosphorous acid and/or phosphonic acids or a derivative thereof are added to the esterification or transesterification batch as a completing agent in an amount which is 100% of the amount equivalent to the transesterification catalyst employed and up to 99% of the amount equivalent to the cobalt to be employed, up to 80 ppm of cobalt in the form of a cobalt compound are then added to the batch, and the polycondensation is carried out without the addition of antimony, in the presence of 1 to 10 ppm of titanium, which is added in the form of a titanium compound, and if appropriate in the presence of up to 1000 ppm of organic compounds which donate crosslinking structural groups (pentaerythritol) and if appropriate up to 50 ppm of an optical brightener, is described. The polyester obtainable by this process is furthermore described.
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