发明授权
US06849202B2 COMPOUND HAVING PHENYLACETYLENE STRUCTURE, LIQUID CRYSTAL COMPOSITION, POLYMER, OPTICALLY ANISOTROPIC PRODUCT, OPTICAL OR LIQUID CRYSTAL ELEMENT, DIBENZOTHIOPHENE COMPOUND, INTERMEDIATE, AND PROCESS FOR PRODUCING THE SAME
失效
具有苯乙烯结构的化合物，液晶组合物，聚合物，光学异相产物，光学或液体晶体元素，二苯并噻吩化合物，中间体及其制备方法
- 专利标题： COMPOUND HAVING PHENYLACETYLENE STRUCTURE, LIQUID CRYSTAL COMPOSITION, POLYMER, OPTICALLY ANISOTROPIC PRODUCT, OPTICAL OR LIQUID CRYSTAL ELEMENT, DIBENZOTHIOPHENE COMPOUND, INTERMEDIATE, AND PROCESS FOR PRODUCING THE SAME
- 专利标题（中）： 具有苯乙烯结构的化合物，液晶组合物，聚合物，光学异相产物，光学或液体晶体元素，二苯并噻吩化合物，中间体及其制备方法
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申请号： US10067871申请日： 2002-02-08
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公开(公告)号： US06849202B2公开(公告)日： 2005-02-01
- 发明人: Chizu Sekine , Masamitsu Ishitobi , Koichi Fujisawa , Kazunori Iwakura , Masayoshi Minai
- 申请人： Chizu Sekine , Masamitsu Ishitobi , Koichi Fujisawa , Kazunori Iwakura , Masayoshi Minai
- 申请人地址： JP Osaka
- 专利权人： Sumitomo Chemical Company, Limited
- 当前专利权人： Sumitomo Chemical Company, Limited
- 当前专利权人地址： JP Osaka
- 代理机构： Birch, Stewart, Kolasch & Birch, LLP
- 优先权： JP2001-033782 20010209; JP2001-037311 20010214; JP2001-052954 20010227
- 主分类号： C07C43/20
- IPC分类号： C07C43/20 ; C07D333/76 ; C09K19/18 ; C09K19/34 ; C09K19/42 ; C09K19/52 ; C07D495/00 ; C09K19/32 ; C09K19/38 ; C09K19/54
摘要：
There are disclosed novel compounds, liquid crystal compositions, polymers, optically anisotropic products, and optical or liquid crystal elements that have large refractive index anisotropy, mix easily with other liquid crystals, have advantageous stability against light, and exhibit absorption at practically short wavelength in the ultraviolet region. The compounds are represented by the formula (1) and have a phenylacetylene structure, wherein difference ΔE in energy of HOMO of parts (1-1), (1-2) and (1-3) calculated by the method of molecular orbitals is not less than 0.3 electronvolt, and the polarizability anisotropy Δα of a molecule represented by the formula (1) calculated in the same way is not lower than 500 A.U.: (A1 to A4: H, F, alkyl or alkoxy group of C1 to C10 optionally substituted with F; P1, P2: structure fulfilling the conditions of HOMO energy and polarizability).
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