发明授权
- 专利标题: (Meth) acrylic acid (salt) polymer and its production process
- 专利标题(中): (Meth)丙烯酸(盐)聚合物及其生产工艺
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申请号: US10281971申请日: 2002-10-29
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公开(公告)号: US06900275B2公开(公告)日: 2005-05-31
- 发明人: Takashi Tomita , Tsutomu Yuasa , Hirokatsu Kawakami
- 申请人: Takashi Tomita , Tsutomu Yuasa , Hirokatsu Kawakami
- 申请人地址: JP Osaka
- 专利权人: Nippon Shokubai Co., Ltd.
- 当前专利权人: Nippon Shokubai Co., Ltd.
- 当前专利权人地址: JP Osaka
- 代理机构: Roylance, Abrams, Berdo & Goodman, L.L.P.
- 优先权: JP2001-340301 20011106
- 主分类号: C04B24/26
- IPC分类号: C04B24/26 ; C08F2/00 ; C08F4/40 ; C08F220/04 ; C08F220/28 ; C08F290/06 ; C08F283/06
摘要:
There is provided: a (meth)acrylic acid (salt) polymer which has high properties and is little colored; and a process which can produce this polymer with a high polymerization conversion without causing the corrosion of the reaction vessel. When a (meth)acrylic acid (salt) polymer is obtained by carrying out polymerization of an unsaturated monocarboxylic monomer (a) and an unsaturated polyalkylene glycolic monomer (b) with a polymerization initiator, either a redox polymerization initiator including hydrogen peroxide and a reducing agent is used as the polymerization initiator in a specific amount, or the unsaturated polyalkylene glycolic monomer is subjected to the polymerization in the form of an esterification reaction product as obtained by a process including the steps of: esterifying the unsaturated monocarboxylic monomer and a polyalkylene glycol in a specific charging ratio in the presence of an acid catalyst in a manner for a portion of the residual unsaturated monocarboxylic monomer as a starting raw material to remain; and then neutralizing the acid catalyst and the residual unsaturated monocarboxylic monomer (a) with a basic substance after the esterification; and the polymerization is carried out under conditions where the pH during the polymerization is in the range of 3.2 to 7.0.
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