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US06927262B2 Bridged biphospholes and metallocenes prepared therefrom 失效
由其制备的桥连双孔和金属茂

Bridged biphospholes and metallocenes prepared therefrom
Abstract:
The invention relates to novel bridged biphosphole ligands according to the general formula: where R2, R3, R4 are chosen from hydrogen, alkyl, aryl or silyl, R1 is chosen from hydrogen, alkyl, aryl or halogen, R1 possibly being replaced with a direct bond between the two phosphorus atoms and T is a divalent group. The invention also relates to metallocenes obtained from these ligands. These metallocenes are useful as catalytic components for the polymerization of olefins.
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