- 专利标题: Fluorinated polycycles and their use in liquid-crystal mixtures
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申请号: US10903082申请日: 2004-07-30
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公开(公告)号: US06955838B2公开(公告)日: 2005-10-18
- 发明人: Rainer Wingen , Barbara Hornung , Wolfgang Schmidt
- 申请人: Rainer Wingen , Barbara Hornung , Wolfgang Schmidt
- 申请人地址: CH Muttenz
- 专利权人: Clariant International Ltd.
- 当前专利权人: Clariant International Ltd.
- 当前专利权人地址: CH Muttenz
- 代理机构: Frommer Lawrence & Haug LLP
- 优先权: DE10336016 20030801
- 主分类号: C07D307/77
- IPC分类号: C07D307/77 ; C09K19/34 ; C09K19/52 ; C07C23/46 ; C07D549/457 ; C09K19/61 ; C09K19/62
摘要:
Compounds of the formula (I) where: R1, R2 are each independently a) H b) -M1-A1-R5 c) a straight-chain or branched alkyl radical having from 1 to 16 carbon atoms or a straight-chain or branched alkenyl radical having from 2 to 16 carbon atoms, where c1) one or more nonadjacent and nonterminal CH2 groups may be replaced by —O—, —C(═O)O—, —O—C(═O)—, —O—C(═O)—O—, —C(═O)— or —Si(CH3)2—, and/or c2) one CH2 group may be replaced by —C≡C—, cyclopropane-1,2-diyl, cyclobutane-1,3-diyl, cyclohexane-1,4-diyl or phenylene-1,4-diyl, and/or c3) one or more hydrogen atoms may be replaced by F and/or Cl, p, q, r are each independently 0 or 1 M1—is —CO—O—, —O—CO—, —CH2—O—, —O—CH2—, —CF2—O—, —O—CF2—, —CH═CH—, —CF═CF—, —C≡C—, —CH2—CH2—CO—O—, —O—CO—CH2—CH2—, —CH2—CH2—, —CF2—CF2—, —(CH2)4—, —OC(═O)CF═CF— or a single bond, A1 is 1,4-phenylene where one or two hydrogen atoms may be replaced by F, Cl, CN and/or OCF3, or up to three hydrogen atoms may be replaced by fluorine, 1,4-cyclohexylene where one or two hydrogen atoms may be replaced by CH3 and/or F, 1-cyclohexene-1,4-diyl where one hydrogen atom may be replaced by CH3 or F, or 1,3-dioxane-2,5-diyl, R5 has the same possible definitions as R1 and R2 with the exception of -M1-A1-R5, with the provisos that: a) at least one of p, q, r is 1 b) R1 and R2 must not at the same time be H are used in liquid-crystal mixtures.
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