发明授权
- 专利标题: Use of a supplemental promoter in conjunction with a carbon-supported noble-metal-containing catalyst in liquid phase oxidation reactions
- 专利标题(中): 在液相氧化反应中使用补充促进剂与含碳负载的含贵金属的催化剂结合使用
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申请号: US10427830申请日: 2003-05-01
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公开(公告)号: US06963009B2公开(公告)日: 2005-11-08
- 发明人: Mark A. Leiber , Jerry R. Ebner , Kam-To Wan , Anthony Woods , Peter Rogers
- 申请人: Mark A. Leiber , Jerry R. Ebner , Kam-To Wan , Anthony Woods , Peter Rogers
- 申请人地址: US MO St. Louis
- 专利权人: Monsanto Technology LLC
- 当前专利权人: Monsanto Technology LLC
- 当前专利权人地址: US MO St. Louis
- 代理机构: Senniger Powers
- 代理商 Joseph A. Schaper
- 主分类号: A01N57/20
- IPC分类号: A01N57/20 ; B01J21/18 ; B01J23/56 ; B01J37/02 ; C07B61/00 ; C07F9/38 ; C07F9/28 ; C07C53/02
摘要:
This invention relates to the use of a supplemental promoter in conjunction with a noble-metal-containing catalyst comprising a carbon support in catalyzing liquid phase oxidation reactions.In a particularly preferred embodiment, a supplemental promoter (most preferably bismuth or tellurium) is used in conjunction with a noble-metal-containing catalyst comprising a carbon support in a liquid phase oxidation process wherein N-(phosphonomethyl) iminodiacetic acid (i.e., “PMIDA”) or a salt thereof is oxidized to form N-(phosphonomethyl)glycine (i.e., “glyphosate”) or a salt thereof. The benefits of such a process include oxidation of the formaldehyde and formic acid by-products, and, consequently, decreased final concentrations of those by-products as well as other undesirable by-products, most notably N-methyl-N-(phosphonomethyl)glycine (i.e., “NMG”).
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