发明授权
US06963009B2 Use of a supplemental promoter in conjunction with a carbon-supported noble-metal-containing catalyst in liquid phase oxidation reactions 有权
在液相氧化反应中使用补充促进剂与含碳负载的含贵金属的催化剂结合使用

Use of a supplemental promoter in conjunction with a carbon-supported noble-metal-containing catalyst in liquid phase oxidation reactions
摘要:
This invention relates to the use of a supplemental promoter in conjunction with a noble-metal-containing catalyst comprising a carbon support in catalyzing liquid phase oxidation reactions.In a particularly preferred embodiment, a supplemental promoter (most preferably bismuth or tellurium) is used in conjunction with a noble-metal-containing catalyst comprising a carbon support in a liquid phase oxidation process wherein N-(phosphonomethyl) iminodiacetic acid (i.e., “PMIDA”) or a salt thereof is oxidized to form N-(phosphonomethyl)glycine (i.e., “glyphosate”) or a salt thereof. The benefits of such a process include oxidation of the formaldehyde and formic acid by-products, and, consequently, decreased final concentrations of those by-products as well as other undesirable by-products, most notably N-methyl-N-(phosphonomethyl)glycine (i.e., “NMG”).
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