Invention Grant
US06964937B2 Bimetallic catalyst for producing polyethylene resins with bimodal molecular weight distribution, its preparation and use
失效
用于生产具有双峰分子量分布的聚乙烯树脂的双金属催化剂,其制备和用途
- Patent Title: Bimetallic catalyst for producing polyethylene resins with bimodal molecular weight distribution, its preparation and use
- Patent Title (中): 用于生产具有双峰分子量分布的聚乙烯树脂的双金属催化剂,其制备和用途
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Application No.: US10433228Application Date: 2001-04-10
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Publication No.: US06964937B2Publication Date: 2005-11-15
- Inventor: Robert Ivan Mink , Thomas Edward Nowlin , Pradeep P. Shirodkar , Gary M. Diamond , David Bruce Barry , Chunming Wang , Hitesh A. Fruitwala , Shih-May Christine Ong
- Applicant: Robert Ivan Mink , Thomas Edward Nowlin , Pradeep P. Shirodkar , Gary M. Diamond , David Bruce Barry , Chunming Wang , Hitesh A. Fruitwala , Shih-May Christine Ong
- Applicant Address: US TX Houston
- Assignee: Univation Technologies, LLC
- Current Assignee: Univation Technologies, LLC
- Current Assignee Address: US TX Houston
- Agent Kevin M. Faulkner
- International Application: PCT/US01/31075 WO 20010410
- International Announcement: WO02/44222 WO 20020606
- Main IPC: C08F4/634
- IPC: C08F4/634 ; C08F4/6392 ; C08F4/64 ; C08F4/642 ; C08F4/659 ; C08F4/6592 ; C08F10/00 ; C08F10/02 ; C08F210/02 ; C08F210/16 ; C08F4/602 ; C08F4/626 ; C08F4/629

Abstract:
Bimetallic catalyst for producing polyethylene resins with a bimodal molecular weight distribution, its preparation and use. The catalyst is obtainable by a process which includes contacting a support material with an organomagnesium component and carbonyl-containing component. The support material so treated is contacted with a non-metallocene transition metal component to obtain a catalyst intermediate, the latter being contacted with an aluminoxane component and a metallocene component. This catalyst may be further activated with, e.g., alkylaluminum cocatalyst, and contacted, under polymerization conditions, with ethylene and optionally one or more comonomers, to produce ethylene homo- or copolymers with a bimodal molecular weight distribution and improved resin swell properties in a single reactor. These ethylene polymers are particularly suitable for blow molding applications.
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