发明授权
US06989455B2 Two-stage process for the hydrogenation of maleic acid to 1,4-butanediol
有权
将马来酸氢化成1,4-丁二醇的两阶段方法
- 专利标题: Two-stage process for the hydrogenation of maleic acid to 1,4-butanediol
- 专利标题(中): 将马来酸氢化成1,4-丁二醇的两阶段方法
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申请号: US10645429申请日: 2003-08-21
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公开(公告)号: US06989455B2公开(公告)日: 2006-01-24
- 发明人: Robert P. Hepfer , Craig T. Miller , Gregory A. Norenberg , Thomas G. Attig , John R. Budge
- 申请人: Robert P. Hepfer , Craig T. Miller , Gregory A. Norenberg , Thomas G. Attig , John R. Budge
- 申请人地址: US DE Wilmington
- 专利权人: ISP Investments Inc.
- 当前专利权人: ISP Investments Inc.
- 当前专利权人地址: US DE Wilmington
- 代理商 William J. Davis; David P. Yusko
- 主分类号: C07D307/02
- IPC分类号: C07D307/02 ; C07D307/58 ; C07D307/60 ; C07D407/00 ; C07C409/00
摘要:
In the process for the conversion of maleic acid to gamma-butyrolactone, 1.4-butanediol and/or tetrahydrofuran, a feedstream comprising maleic acid is hydrogenated in a first hydrogenation zone to produce a reaction product comprising succinic acid and unreacted hydrogen which is then supplied to a second hydrogenation zone, where succinic acid is converted to 1,4-butanediol, the temperatures of the feedstream comprising maleic acid and the first hydrogenation zone are controlled such that the temperature of maleic acid in the feedstream and the first hydrogenation zone does not exceed about 130° C., thereby minimizing the corrosive effects of the maleic acid and prolonging reactor life and improving overall process economics.
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