发明授权
- 专利标题: Modified polymers prepared with lanthanide-based catalysts
- 专利标题(中): 用镧系元素催化剂制备的改性聚合物
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申请号: US10296084申请日: 2000-11-10
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公开(公告)号: US06992147B1公开(公告)日: 2006-01-31
- 发明人: Yoichi Ozawa , H. Jerrold Miller , Koji Masaki , Tatsuo Fujimaki , Takuo Sone , Iwakazu Hattori , Koichi Morita
- 申请人: Yoichi Ozawa , H. Jerrold Miller , Koji Masaki , Tatsuo Fujimaki , Takuo Sone , Iwakazu Hattori , Koichi Morita
- 申请人地址: JP Tokyo
- 专利权人: Bridgestone Corporation
- 当前专利权人: Bridgestone Corporation
- 当前专利权人地址: JP Tokyo
- 代理商 Arthur M. Reginelli
- 国际申请: PCT/US00/30743 WO 20001110
- 国际公布: WO01/34658 WO 20010517
- 主分类号: C08C19/00
- IPC分类号: C08C19/00 ; C08F8/00
摘要:
A method for preparing a functionalized polymer comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, and reacting the pseudo-living polymer with at least one functionalizing agent defined by the formula (I) where A is a substituent that will undergo an addition reaction with a pseudo-living polymer, R1 is a divalent organic group, R2 is a monovalent organic group, and each R4, which may be the same or different, is a monovalent organic group or a substituent defined by —OR5 where R5 is a monovalent organic group, with the proviso that A, R1, R2, R4, and R5 are substituents that will not protonate a pseudo-living polymer. Also, the functionalized polymer and a vulcanizable composition containing the polymer.
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