发明授权
US07049442B2 Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins
失效
用于乙烯低聚至直链α-烯烃的配体及其催化剂体系
- 专利标题: Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins
- 专利标题(中): 用于乙烯低聚至直链α-烯烃的配体及其催化剂体系
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申请号: US10208535申请日: 2002-07-30
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公开(公告)号: US07049442B2公开(公告)日: 2006-05-23
- 发明人: Eric Johannes Maria De Boer , Harry Van Der Heijden , Wihelmina Cornelia Verhoef-Van Wijk , Arie Van Zon
- 申请人: Eric Johannes Maria De Boer , Harry Van Der Heijden , Wihelmina Cornelia Verhoef-Van Wijk , Arie Van Zon
- 申请人地址: US TX Houston
- 专利权人: Shell Oil Company
- 当前专利权人: Shell Oil Company
- 当前专利权人地址: US TX Houston
- 优先权: EP01306607 20010801
- 主分类号: C07D213/53
- IPC分类号: C07D213/53 ; C07D401/12 ; C07D402/12 ; C07D217/12 ; C07C2/24
摘要:
Mixed bis-imine pyridine ligands of formula (I), wherein Z1, which is different from Z2, is an optionally substituted aryl group; and Z2 comprises an optionally substituted heterohydrocarbyl moiety, or an optionally substituted aryl group in combination with a metal, said optionally substituted aryl group being π-co-ordinated to the metal; mixed bis-imine pyridine complexes comprising a ligand of formula (I); mixed ionic bis-imine pyridine complexes comprising a ligand of formula (I); and processes for the production of alpha olefins from ethylene, using said complexes.
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