发明授权
- 专利标题: Method for purification of as-produced single-wall carbon nanotubes
- 专利标题(中): 纯化生产的单壁碳纳米管的方法
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申请号: US10028231申请日: 2001-12-21
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公开(公告)号: US07115864B2公开(公告)日: 2006-10-03
- 发明人: Daniel T. Colbert , Hongjie Dai , Jason H. Hafner , Andrew G. Rinzler , Richard E. Smalley , Jie Liu , Kenneth A. Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
- 申请人: Daniel T. Colbert , Hongjie Dai , Jason H. Hafner , Andrew G. Rinzler , Richard E. Smalley , Jie Liu , Kenneth A. Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
- 申请人地址: US TX Houston
- 专利权人: William Marsh Rice University
- 当前专利权人: William Marsh Rice University
- 当前专利权人地址: US TX Houston
- 代理机构: Winstead Sechrest & Minick P.C.
- 代理商 Ross Spencer Garsson; Edward T. Mickelson
- 主分类号: G01N23/00
- IPC分类号: G01N23/00
摘要:
This invention relates generally to a single-wall carbon nanotube (SWNT) purification process and more particularly to a purification process that comprises heating the SWNT-containing felt under oxidizing conditions to remove the amorphous carbon deposits and other contaminating materials. In a preferred mode of this purification procedure, the felt is heated in an aqueous solution of an inorganic oxidant, such as nitric acid, a mixture of hydrogen peroxide and sulfuric acid, or a potassium permanganate. Preferably, SWNT-containing felts are refluxed in an aqueous solution of an oxidizing acid at a concentration high enough to etch away amorphous carbon deposits within a practical time frame, but not so high that the single-wall carbon nanotube material will be etched to a significant degree. When material having a high proportion of SWNT is purified, the preparation produced will be enriched in single-wall nanotubes, so that the SWNT are substantially free of other material.
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