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US07129302B2 Bimetallic catalyst for producing polyethylene resins with bimodal molecular weight distribution, its preparation and use 失效
用于生产具有双峰分子量分布的聚乙烯树脂的双金属催化剂,其制备和用途

Bimetallic catalyst for producing polyethylene resins with bimodal molecular weight distribution, its preparation and use
摘要:
Bimetallic catalyst for producing polyethylene resins with a bimodal molecular weight distribution, its preparation and use. The catalyst is obtainable by a process which includes contacting a support material with an organomagnesium component and carbonyl-containing component. The support material so treated is contacted with a non-metallocene transition metal component to obtain a catalyst intermediate, the latter being contacted with an aluminoxane component and a metallocene component, This catalyst may be further activated with, e.g., alkylaluminum cocatalyst, and contacted, under polymerization conditions, with ethylene and optionally one or more comonomers, to produce ethylene homo- or copolymers with a bimodal molecular weight distribution and improved resin swell properties in a single reactor. These ethylene polymers are particularly suitable for blow molding applications.
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