发明授权
- 专利标题: Apparatus for and method of producing aromatic carboxylic acids
- 专利标题(中): 芳香族羧酸的制造方法及其制造方法
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申请号: US10443542申请日: 2003-05-22
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公开(公告)号: US07153480B2公开(公告)日: 2006-12-26
- 发明人: David Robert Bickham , Michael Cooke , Martin Reid Burton Davis , Samuel Duncan Housley , Finbar Gerald McDonnell
- 申请人: David Robert Bickham , Michael Cooke , Martin Reid Burton Davis , Samuel Duncan Housley , Finbar Gerald McDonnell
- 代理商 Charles E. Krukiel
- 主分类号: B01J19/18
- IPC分类号: B01J19/18
摘要:
A reactor for the oxidation of a precursor to an aromatic carboxylic acid or ester thereof in a liquid phase reaction mixture is disclosed. The reactor comprises an elongate vessel, substantially vertical in use, having an upper mixing element and a lower mixing element, characterised in that the upper mixing element is an axial pumping impeller and the lower mixing element is a radial pumping impeller. A process of producing a carboxylic acid or ester thereof in a reactor of the invention is also disclosed. In use, the configuration of mixing elements leads to three highly turbulent mixing zones. In a preferred embodiment of the process of the present invention oxidant, from one inlet, and solvent, precursor and catalyst, are introduced directly into a mixing zone. The highly turbulent mixing zones lead to rapid mass transfer suppressing the formation of unwanted, coloured by-products and reduced reactor fouling.
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