发明授权
- 专利标题: Process of continuously producing polyesters or copolyesters
- 专利标题(中): 连续生产聚酯或共聚酯的工艺
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申请号: US10451292申请日: 2001-11-27
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公开(公告)号: US07153927B2公开(公告)日: 2006-12-26
- 发明人: Fritz Wilhelm , Michael Reisen
- 申请人: Fritz Wilhelm , Michael Reisen
- 申请人地址: DE Frankfurt Main
- 专利权人: Zimmer AG
- 当前专利权人: Zimmer AG
- 当前专利权人地址: DE Frankfurt Main
- 代理机构: Norris McLaughlin & Marcus PA
- 优先权: DE10064361 20001221; DE10127147 20010602
- 国际申请: PCT/EP01/13776 WO 20011127
- 国际公布: WO02/50159 WO 20020627
- 主分类号: C08G63/00
- IPC分类号: C08G63/00
摘要:
Process for producing polyesters and copolyesters, wherein a continuous esterification of dicarboxylic esters and diols or a continuous transesterification of dicarboxylic esters with diols is effected in “n” reaction pressure stages connected in series, the pressure in the first reaction pressure stage is higher than that of the remaining reaction pressure stages, and successively decreases from reaction pressure stage to succeeding reaction pressure stage, the combined vapor flows of the individual reaction pressure stages are rectified in a rectifying column, and the diol component obtained at the bottom of the rectifying column is recirculated at least to the first reaction pressure stage, and wherein at least the last reaction pressure stage operates at a vacuum, the pressure in the rectifying column is greater than that of the last reaction pressure stage, and the vapors discharged from the last reaction pressure stage are condensed to the pressure existing in the rectifying column.
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