发明授权
US07183423B1 Process for the preparation of organic compounds with imide catalysts
失效
用酰亚胺催化剂制备有机化合物的方法
- 专利标题: Process for the preparation of organic compounds with imide catalysts
- 专利标题(中): 用酰亚胺催化剂制备有机化合物的方法
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申请号: US09622001申请日: 1999-12-09
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公开(公告)号: US07183423B1公开(公告)日: 2007-02-27
- 发明人: Yasutaka Ishii , Takahiro Iwahama , Tatsuya Nakano
- 申请人: Yasutaka Ishii , Takahiro Iwahama , Tatsuya Nakano
- 申请人地址: JP Osaka
- 专利权人: Daicel Chemical Industries, Ltd.
- 当前专利权人: Daicel Chemical Industries, Ltd.
- 当前专利权人地址: JP Osaka
- 代理机构: Birch, Stewart, Kolasch & Birch, LLP
- 优先权: JP10-353621 19981211; JP10-353622 19981211; JP11-065651 19990311; JP11-136340 19990517
- 国际申请: PCT/JP99/06891 WO 19991209
- 国际公布: WO00/35835 WO 20000622
- 主分类号: C07D305/12
- IPC分类号: C07D305/12 ; C07D307/32 ; C07D307/34 ; C07D307/56
摘要:
(A) A compound capable of forming a stable radical and selected from (A1) oxygen-atom-containing compounds each having a carbon-hydrogen bond at the adjacent position to an oxygen atom, (A2) carbonyl-group-containing compounds, and (A3) compounds each having a hydrocarbon group with a methine carbon atom is allowed to react with (B) a radical scavenging compound selected from, for example, (B1) unsaturated compounds, and (B2) compounds each having a hydrocarbon group with a methine carbon atom, in the presence of molecular oxygen by catalysis of, for example, an imide compound shown by the following formula (1): wherein each of R1 and R2 is a hydrogen atom or the like, where R1 and R2 may be combined to form a double bond, or an aromatic or non-aromatic ring; X is an oxygen atom or a hydroxyl group, to yield a product of an addition or substitution reaction of the compound (A) and the compound (B) or its oxidized product. The process can efficiently produce a variety of organic compounds by an addition or substitution reaction using molecular oxygen under mild conditions.