发明授权
US07186783B2 Process for preparaing partially hydrogenated butadiene polymers 有权
制备部分氢化丁二烯聚合物的方法

  • 专利标题: Process for preparaing partially hydrogenated butadiene polymers
  • 专利标题(中): 制备部分氢化丁二烯聚合物的方法
  • 申请号: US10110921
    申请日: 2001-07-25
  • 公开(公告)号: US07186783B2
    公开(公告)日: 2007-03-06
  • 发明人: Wouter De Jong
  • 申请人: Wouter De Jong
  • 申请人地址: US TX Houston
  • 专利权人: Kraton Polymers U.S. LLC
  • 当前专利权人: Kraton Polymers U.S. LLC
  • 当前专利权人地址: US TX Houston
  • 代理商 Keith M. Tackett; Michael A. Masse
  • 优先权: EP00306435 20000728
  • 国际申请: PCT/EP01/08607 WO 20010725
  • 国际公布: WO02/34799 WO 20020502
  • 主分类号: C08F8/04
  • IPC分类号: C08F8/04
Process for preparaing partially hydrogenated butadiene polymers
摘要:
The present invention relates to a process for preparing a partially hydrogenated butadiene polymer comprising no more than 3 mol % 1,2-butadiene-recurring units (A) and no more than 3 mol % ethylene recurring units (D), calculated on the total content mol/mol of recurring units, wherein a butadiene polymer comprising 1,2-butadiene recurring units (A) and 1,4-butadiene recurring units (B) is hydrogenated in the presence of hydrogen and a titanium-, zirconium- and/or hafnium-based metallocene compound as hydrogenation catalyst and a cocatalyst, characterized in that: a) the hydrogenation catalyst has a reaction rate ratio of r1/r2 greater than 5, wherein r1 and r2 are the hydrogenation rates of recurring units (A) and (B) respectively at the same reaction conditions, b) the cocatalyst is an alkali metal hydride, added as such or prepared in situ, and c) hydrogenation of the conjugated diene is carried out until at least 97% of recurring units (A) have been hydrogenated.
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