发明授权
- 专利标题: Process for preparing a stabilized polyester
- 专利标题(中): 制备稳定聚酯的方法
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申请号: US10472789申请日: 2002-03-19
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公开(公告)号: US07205379B2公开(公告)日: 2007-04-17
- 发明人: Dirk Simon , Dari Lazzari , Stephen Mark Andrews , Heinz Herbst
- 申请人: Dirk Simon , Dari Lazzari , Stephen Mark Andrews , Heinz Herbst
- 申请人地址: US NY Tarrytown
- 专利权人: Ciba Specialty Chemicals Corp.
- 当前专利权人: Ciba Specialty Chemicals Corp.
- 当前专利权人地址: US NY Tarrytown
- 代理商 Tyler A. Stevenson
- 优先权: EP01810316 20010328
- 国际申请: PCT/EP02/03006 WO 20020319
- 国际公布: WO02/079310 WO 20021010
- 主分类号: C08G63/16
- IPC分类号: C08G63/16 ; C08G66/00 ; C08G66/68 ; C08G79/02 ; B29D22/00 ; B29D23/00 ; B32B1/00 ; B32B27/00
摘要:
The present invention discloses a process for the preparation of a stabilized polyester that is low in the generation of aldehydes which comprises reacting one or more diacids with one or more diols in an esterification process, and/or one or more diesters with one or more diols in a transesterification process in the presence of an effective amount of a stabilizer selected from the group consisting of (a) a polyhydric alcohol which is for example poly(ethylene-co-vinyl alcohol), poly(styrene-co-allyl alcohol), maltitol, isomalt, sorbitol, xylitol, sucrose, mucic acid dibutylester, mucic acid di(phenyl-1-ethyl)ester, pentaerythritol or dipentaerythritol; (b) a compound of the formula II, which is for example di-iso-octyl-phosphinic acid; (c) a sterically hindered amine which is for example Tinuvin 123 or Tinuvin 622; (d) a polyacrylamide or a cationic acrylamide copolymer; or (e) a hydroxyamine and/or a nitrone. Such polyesters, for example PET, when extrusion compounded exhibit a lower residual acetaldehyde content than does PET alone when similarly treated. The invention pertains to any polyester used in the manufacture of bottles or containers which in turn are used to store consumer materials, especially food, pharmaceuticals, beverages and most especially water
公开/授权文献
- US20040106767A1 Process for preparing a stabilized polyester 公开/授权日:2004-06-03
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