发明授权
US07253300B2 Production process for high purity tricyclo-[5.2.1.02,6]decane-2-carboxylic acid ester
有权
高纯度三环[5.2.1.02,6]癸烷-2-羧酸酯的制备方法
- 专利标题: Production process for high purity tricyclo-[5.2.1.02,6]decane-2-carboxylic acid ester
- 专利标题(中): 高纯度三环[5.2.1.02,6]癸烷-2-羧酸酯的制备方法
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申请号: US10942880申请日: 2004-09-17
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公开(公告)号: US07253300B2公开(公告)日: 2007-08-07
- 发明人: Mitsuharu Kitamura , Takashi Kojima , Yoshiharu Ataka , Tomoaki Kubota , Kinji Kato , Kazuyuki Fukuda
- 申请人: Mitsuharu Kitamura , Takashi Kojima , Yoshiharu Ataka , Tomoaki Kubota , Kinji Kato , Kazuyuki Fukuda
- 申请人地址: JP Tokyo JP Tokyo
- 专利权人: Mitsubishi Gas Chemical Company, Inc.,Kao Corporation
- 当前专利权人: Mitsubishi Gas Chemical Company, Inc.,Kao Corporation
- 当前专利权人地址: JP Tokyo JP Tokyo
- 代理机构: Antonelli, Terry, Stout & Kraus, LLP.
- 优先权: JP2003-327577 20030919; JP2003-327579 20030919; JP2003-327580 20030919
- 主分类号: C07C67/36
- IPC分类号: C07C67/36 ; C07C69/74
摘要:
In a process for producing tricyclo[5.2.1.02,6]decane-2-carboxylic acid ester by reacting tricyclo[5.2.1.02,6]deca-3-ene with carbon monoxide and alcohol in the presence of HF, carried out separately are (a) a step in which tricyclo[5.2.1.02,6]deca-3-ene is reacted with carbon monoxide to produce acyl fluoride and (b) a step in which acyl fluoride obtained in the step described above is reacted with alcohol to produce an ester. Also, the reaction conditions at the step (a) described above are selected or a step for carrying out isomerization reaction of tricyclo[5.2.1.02,6]decane-2-carboxylic fluoride obtained at the step (a) is interposed between the step (a) and the step (b). Further, the crude product of tricyclo[5.2.1.02,6]decane-2-carboxylic acid ester thus obtained is subjected to contact treatment with specific glycol in the presence of an acid catalyst and then distilled.