发明授权
US07304159B2 Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins 失效
用于乙烯低聚至直链α-烯烃的配体及其催化剂体系

Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins
摘要:
Mixed bis-imine pyridine ligands of formula (I), wherein Z1, which is different from Z2, is an optionally substituted aryl group; and Z2 comprises an optionally substituted heterohydrocarbyl moiety, or an optionally substituted aryl group in combination with a metal, said optionally substituted aryl group being π-co-ordinated to the metal; mixed bis-imine pyridine complexes comprising a ligand of formula (I); mixed ionic bis-imine pyridine complexes comprising a ligand of formula (I); and processes for the production of alpha olefins from ethylene, using said complexes.
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