Invention Grant
US07342135B2 3(4),7(8)-Bis(aminomethyl)bicyclo[4.3.0]nonane and a process for its preparation 失效
3(4),7(8) - 双(氨基甲基)双环[4.3.0]壬烷及其制备方法

3(4),7(8)-Bis(aminomethyl)bicyclo[4.3.0]nonane and a process for its preparation
Abstract:
3(4),7(8)-bis(aminomethyl)bicyclo[4.3.0]nonane and a process for its preparation, wherein bicyclo[4.3.0]nona-3,7-diene is reacted with synthesis gas in a homogeneous organic phase in the presence of transition metal compounds of Group VIII of the Periodic Table containing complex-bound organophosphorus compounds, and excess organophosphorus compound, at temperatures of 70 to 160° C. and pressures of 5 to 35 MPa, and the 3(4),7(8)-bisformylbicyclo[4.3.0]nonane thus obtained is reductively aminated.
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