发明授权
- 专利标题: Isotactic propylene copolymer fibers, their preparation and use
- 专利标题(中): 全同立构丙烯共聚物纤维,其制备和用途
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申请号: US11669342申请日: 2007-01-31
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公开(公告)号: US07344775B2公开(公告)日: 2008-03-18
- 发明人: James C. Stevens , Daniel D. Vanderlende , Samuel Ethiopia
- 申请人: James C. Stevens , Daniel D. Vanderlende , Samuel Ethiopia
- 申请人地址: US MI Midland
- 专利权人: Dow Global Technologies Inc.
- 当前专利权人: Dow Global Technologies Inc.
- 当前专利权人地址: US MI Midland
- 代理机构: Whyte Hirschboeck Dudek SC
- 主分类号: D01F6/30
- IPC分类号: D01F6/30 ; C08F210/06
摘要:
Fibers comprising a propylene homopolymer or a copolymer of propylene and at least one of ethylene and one or more unsaturated comonomers exhibit desirable properties. The homopolymers are characterized as having 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity. The copolymers are characterized as (A) comprising at least about 60 weight percent (wt %) of units derived from propylene, and (B) having at least one of the following properties: (i) 13C NMR peaks corresponding to a regio-error at about 14.6 and about 15.7 ppm, the peaks of about equal intensity, (ii) a B-value greater than about 1.4 when the comonomer content of the copolymer is at least about 3 wt %, (iii) a skewness index, Six, greater than about −1.20, (iv) a DSC curve with a Tme that remains essentially the same and a Tmax that decreases as the amount of comonomer in the copolymer is increased, and (v) an X-ray diffraction pattern that reports more gamma-form crystals than a comparable copolymer prepared with a Ziegler-Natta (Z-N) catalyst.
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