发明授权
- 专利标题: Process for cracking an olefin-rich hydrocarbon feedstock
- 专利标题(中): 裂化烯烃富烃原料的方法
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申请号: US10398603申请日: 2001-10-03
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公开(公告)号: US07375257B2公开(公告)日: 2008-05-20
- 发明人: Jean-Pierre Dath , Walter Vermeiren
- 申请人: Jean-Pierre Dath , Walter Vermeiren
- 申请人地址: BE Feluy
- 专利权人: Total Petrochemicals Research Feluy
- 当前专利权人: Total Petrochemicals Research Feluy
- 当前专利权人地址: BE Feluy
- 代理商 Shirley A. Kopecky; William D. Jackson
- 优先权: EP00121727 20001005
- 国际申请: PCT/EP01/11487 WO 20011003
- 国际公布: WO02/28987 WO 20020411
- 主分类号: C07C4/02
- IPC分类号: C07C4/02 ; C10G11/02
摘要:
A process for cracking an olefin containing hydrocarbon feedstock which is selective towards light olefins in the effluent, the process comprising passing a hydrocarbon feedstock containing one or more olefins through a moving bed reactor containing a crystalline silicate catalyst selected from an MFI-type crystalline silicate having a silicon/aluminium atomic ratio of at least 180 and an MEL-type crystalline silicate having a silicon/aluminium atomic ration of from 150 to 800 which has been subjected to a steaming step, at an inlet temperature of from 500 to 600° C., at an olefin partial pressure of from 0.1 to 2 bars and the feedstock being passed over the catalyst at an LHSV of from 5 to 30 h−1 to produce an effluent with an olefin content of lower molecular weight than that of the feedstock, intermittently removing a first fraction of the catalyst from the moving bed reactor, regenerating the first fraction of the catalyst in a regenerator and intermittently feeding into the moving bed reactor a second fraction of the catalyst which has been regenerated in the regenerator, the catalyst regeneration rate being controlled whereby the propylene purity is maintained constant at a value corresponding to the average value observed in a fixed bed reactor using the same feedstock, catalyst and cracking conditions, for example at least 94 wt. %.
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