发明授权
- 专利标题: Method for the production of butadine from n-butane
- 专利标题(中): 从正丁烷生产丁二烯的方法
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申请号: US11721240申请日: 2005-12-07
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公开(公告)号: US07435860B2公开(公告)日: 2008-10-14
- 发明人: Sven Crone , Catharina Klanner , Götz-Peter Schindler , Mark Duda , Frieder Borgmeier
- 申请人: Sven Crone , Catharina Klanner , Götz-Peter Schindler , Mark Duda , Frieder Borgmeier
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF SE
- 当前专利权人: BASF SE
- 当前专利权人地址: DE Ludwigshafen
- 代理机构: Connolly Bove Lodge & Hutz LLP
- 优先权: DE102004059356 20041209
- 国际申请: PCT/EP2005/013105 WO 20051207
- 国际公布: WO2006/061202 WO 20060615
- 主分类号: C07C5/333
- IPC分类号: C07C5/333
摘要:
A process for preparing butadiene, comprising nonoxidatively dehydrogenating n-butane from a stream (a) in a first dehydrogenation zone to obtain stream (b) comprising 1-butene and 2-butene; oxidatively dehydrogenating the 1-butene and 2-butene of (b) in the presence of an oxygenous gas in a second dehydrogenation zone to obtain stream (c) comprising n-butane, butadiene, hydrogen, carbon dioxide, and steam; compressing and cooling (c) to obtain stream (d2) comprising n-butane, butadiene, hydrogen, carbon dioxide, and steam; extractively distilling (d2) into stream (e1) comprising butadiene and stream (e2) comprising n-butane, hydrogen, carbon dioxide, and steam; compressing and cooling (e2) to obtain stream (f1) comprising n-butane and water and stream (f2) comprising n-butane, hydrogen, and carbon dioxide; cooling (f2) to obtain stream (g1) comprising n-butane and stream (g2) comprising carbon dioxide and hydrogen; phase separating water from (f1) to obtain stream (h1) comprising n-butane; and recycling (h1) into the first dehydrogenation zone.
公开/授权文献
- US20080097133A1 Method For The Production Of Butadine From N-Butane 公开/授权日:2008-04-24
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