Invention Grant
- Patent Title: Two stage oxidation process for the production of aromatic dicarboxylic acids
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Application No.: US10156312Application Date: 2002-05-28
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Publication No.: US07485747B2Publication Date: 2009-02-03
- Inventor: Ronald Buford Sheppard , Charles Edwan Sumner, Jr. , Brent Alan Tennant
- Applicant: Ronald Buford Sheppard , Charles Edwan Sumner, Jr. , Brent Alan Tennant
- Applicant Address: US TN Kingsport
- Assignee: Eastman Chemical Company
- Current Assignee: Eastman Chemical Company
- Current Assignee Address: US TN Kingsport
- Agent Steven A. Owen; Dennis V. Carmen; Bernard J. Graves, Jr.
- Main IPC: C07C51/16
- IPC: C07C51/16 ; C07C51/42

Abstract:
Disclosed is a process for producing a benzenedicarrboxylic acid such as terephthalic acid wherein a dialkyl benzene compound and acetic acid having catalyst components dissolved therein are fed to a first reaction zone wherein the dialkyl benzene compound is oxidized with molecular oxygen to provide a first oxidation zone product comprising a benzenedicarboxylic acid containing minor amounts of mono-carboxylic acid by-products such as carboxybenzaldehyde and toluic acid. The first oxidation zone product comprising a slurry of a benzenedicarboxylic acid containing minor amounts of mono-carboxylic acid by-products is fed to a second oxidation reaction zone that is operated under more severe conditions of temperature and pressure. The rate of the feed of a molecular oxygen containing gas to the second oxidation zone is about 3% or less of the the rate of the feed of the molecular oxygen containing gas to the first oxidation zone. The benzenedicarboxylic acid product obtained contains a total concentration of carboxybenzaldehyde and toluic acid of about 150 ppmw or less.
Public/Granted literature
- US20020183546A1 Two stage oxidation process for the production of aromatic dicarboxylic acids Public/Granted day:2002-12-05
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