发明授权
- 专利标题: Method for producing butadiene from n-butane
- 专利标题(中): 从正丁烷生产丁二烯的方法
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申请号: US11722278申请日: 2005-12-19
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公开(公告)号: US07495138B2公开(公告)日: 2009-02-24
- 发明人: Sven Crone , Catharina Klanner , Götz-Peter Schindler , Mark Duda , Frieder Borgmeier
- 申请人: Sven Crone , Catharina Klanner , Götz-Peter Schindler , Mark Duda , Frieder Borgmeier
- 申请人地址: DE Ludwigshafen
- 专利权人: BASF Aktiengesellschaft
- 当前专利权人: BASF Aktiengesellschaft
- 当前专利权人地址: DE Ludwigshafen
- 代理机构: Connolly Bove Lodge & Hutz LLP
- 优先权: DE102004061514 20041221
- 国际申请: PCT/EP2005/013659 WO 20051219
- 国际公布: WO2006/066848 WO 20060629
- 主分类号: C07C5/333
- IPC分类号: C07C5/333
摘要:
A process for preparing butadiene, comprising nonoxidatively dehydrogenating n-butane from a stream (a) in a first dehydrogenation zone to obtain stream (b) comprising 1-butene, 2-butene, and butadiene; oxidatively dehydrogenating the 1-butene and 2-butene of (b) in the presence of an oxygenous gas in a second dehydrogenation zone to obtain stream (c) comprising n-butane, butadiene, hydrogen, and steam; compressing and cooling (c) to obtain stream (d2) comprising n-butane, butadiene, hydrogen, and steam; extractively distilling (d2) into stream (e1) comprising butadiene and stream (e2) comprising n-butane, hydrogen, and steam; optionally compressing and cooling (e2) to obtain stream (f1) comprising n-butane and water and stream (f2) comprising n-butane and hydrogen and optionally recycling (f1) into the first dehydrogenation zone; separating (f2) into stream (g1) comprising n-butane and stream (g2) comprising hydrogen by contacting (f2) with a high boiling absorbent and subsequently desorbing the gas constituents dissolved in the absorbent.
公开/授权文献
- US20080119680A1 Method for Producing Butadiene from N-Butane 公开/授权日:2008-05-22
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