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US07504533B2 Process for the production of isocyanates 有权
生产异氰酸酯的方法

Process for the production of isocyanates
摘要:
Isocyanates are produced by a) reacting at least one amine with phosgene, optionally in the presence of a solvent to produce the corresponding isocyanate and a stream containing hydrogen chloride, phosgene and optionally solvent, low-boiling compounds and inert substances is obtained, b) separating the stream containing hydrogen chloride, phosgene and optionally solvent, low-boiling compounds and inert substances in an at least two-stage sequence of absorption steps that includes (1) at least one isothermal absorption step and (2) at least one adiabatic absorption step, to obtain (i) a hydrogen chloride stream containing phosgene in concentrations of at most 0.5 wt. % (based on the weight of the hydrogen chloride stream) and (ii) a liquid phosgene stream, and c) recycling the liquid phosgene stream (ii) to the reaction of amine with phosgene.
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