A vehicle fuel composition comprises: a light or low-carbon hydrocarbon or pentane fraction; a non-lead anti-knocking agent including methyl tert-butyl ether, tert-amyl methyl ether, anhydrous methanol and anhydrous ethanol; a fluorocarbon cation surfactant and/or a fluorocarbon non-ionic surfactant; which are thoroughly blended to obtain a motor fuel having a research octane number of more than ninety for enhancing anti-knocking property and also for minimizing carbon accumulation in a combustion engine system.