发明授权
US07550544B2 Halogen substituted metallocene compounds for olefin polymerization
有权
用于烯烃聚合的卤素取代的金属茂化合物
- 专利标题: Halogen substituted metallocene compounds for olefin polymerization
- 专利标题(中): 用于烯烃聚合的卤素取代的金属茂化合物
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申请号: US11302821申请日: 2005-12-14
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公开(公告)号: US07550544B2公开(公告)日: 2009-06-23
- 发明人: Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Catalina L. Coker , Jo Ann M. Canich
- 申请人: Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Catalina L. Coker , Jo Ann M. Canich
- 申请人地址: US TX Houston
- 专利权人: ExxonMobil Chemical Patents Inc.
- 当前专利权人: ExxonMobil Chemical Patents Inc.
- 当前专利权人地址: US TX Houston
- 代理商 Catherine L. Bell
- 主分类号: C08F4/64
- IPC分类号: C08F4/64 ; C08F4/76 ; C07F17/00
摘要:
A metallocene compound is represented by the formula (1): wherein: M is a Group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom, preferably a Group 4 transition metal atom selected from titanium, zirconium or hafnium; E is a substituted or unsubstituted monocyclic or polycyclic arenyl ligand pi-bonded to M; A is a substituted or unsubstituted polycyclic arenyl ligand that is pi-bonded to M and has a different ring structure than the E ligand; at least one of the A and E ligands includes at least one halogen substituent directly bonded to an sp2 carbon at a bondable ring position; Y is a bridging group containing at least one Group 13, 14, 15, or 16 element and any single position of the ring structure of A and to any single position of the ring structure of E; and y is zero or 1, indicating the absence (y=0) or presence (y=1) of Y; and each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand; provided that when E is an unsubstituted cyclopentadienyl ligand, either y is one or A is not 2-bromofluorenyl or 2,7-dibromofluorenyl.
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