发明授权
- 专利标题: Process for the continuous removal of hydrogen sulfide from gaseous streams
- 专利标题(中): 从气流中连续除去硫化氢的工艺
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申请号: US12065909申请日: 2006-08-31
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公开(公告)号: US07608231B2公开(公告)日: 2009-10-27
- 发明人: Giuseppe Bellussi , Alberto De Angelis , Paolo Pollesel , Marcello Milli
- 申请人: Giuseppe Bellussi , Alberto De Angelis , Paolo Pollesel , Marcello Milli
- 申请人地址: IT Rome
- 专利权人: ENI S.p.A.
- 当前专利权人: ENI S.p.A.
- 当前专利权人地址: IT Rome
- 代理机构: Oblon, Spivak, McClelland, Maier & Neustadt, L.L.P.
- 优先权: ITMI2005A1647 20050907
- 国际申请: PCT/EP2006/008523 WO 20060831
- 国际公布: WO2007/028539 WO 20070315
- 主分类号: B01D53/48
- IPC分类号: B01D53/48 ; C01B17/16 ; C01B17/04
摘要:
Process for the removal in continuous of hydrogen sulfide from gaseous streams containing it, comprising: a) putting a gas containing H2S in contact with an oxidizing acid aqueous solution of ferric nitrate and containing a heteropolyacid having redox properties; b) filtrating and separating the sulfur produced by the redox reaction; c) oxidizing the ferrous nitrate to ferric nitrate with air; d) recycling the solution containing ferric nitrate and heteropolyacid to the oxidation step (a); e) subjecting the gaseous stream leaving the oxidation reactor (c) to washing with the reduced solution; and f) discharging the gaseous stream.
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